Manufacture of Sulfuric Acid - The Contact Process.
The Effect of using a Catalyst on the Formation of Sulfur Trioxide.
The catalyst for this reaction is
Vanadium(V) oxide
(V2O5).
Transition
metals often make good
catalysts.
The formation of sulfur trioxide is reversible.
sulfur
dioxide + oxygen
sulfur
trioxide
2SO2(g)
+ O2(g)
2SO3(g)
We know
from reaction
rates that a catalyst
can increase the rate
of a reaction.
With a
reversible
reaction, a catalyst
will increase the rate
of both the
forward and the backward reaction.
This is useful because the
catalyst will cause the reaction mixture
to reach its equilibrium
composition more
quickly.
Note, the catalyst will not
change the equilibrium
composition
but it will increase the yield
in a particular time.
In the contact
process
the reactants can be pushed through the
reaction
vessel
more quickly in the presence of a catalyst.
Without the catalyst
the process would take longer
and be
more expensive
(compare this
with the formation of ammonia
in the Haber process).
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