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The Empirical Formula from a Reaction.
Example 2.
20
g of calcium was
found to react with 35·5
g of chlorine.
What is the empirical formula of
calcium chloride?
Method.
1) Find how many
moles of calcium react with
how many moles of chlorine.
RAM of
Ca = 40, RAM of
Cl = 35·5.
moles = mass ÷ RAM
for calcium moles = 20
÷ 40
= 0·5 moles.
for chlorine moles = 35·5
÷ 35·5
= 1·0
moles.
2) The proportion of moles
of calcium to moles of chlorine
is reduced to the lowest whole number.
0·5 moles of Ca to 1·0 moles of
Cl.
Multiply by 2.
1 mole of
Ca to 2
moles of Cl.
The empirical formula is CaCl2.
Since
calcium chloride is an ionic compound,
the actual formula is the same as the empirical formula.
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