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The Periodic Table

The Halogens - Group Trends.

As you go down group 7 from fluorine to astatine, they

1)  Have bigger atoms.
Each successive element has an extra electron shell.
It is the electron shells which take up nearly all the space of an atom.

2)  Are less reactive. Fluorine is the most reactive, astatine the least.
As the size of the atoms increase, the extra outer electron
(which it wants to gain or share to become a stable ion or molecule)
is further and further from the positive nucleus.
It is the attraction between the negative incoming electron
and the positive nucleus
which determines how easily the electron will be gained.
The smaller the atom, the closer the incoming outer electron is,
the more easily it is gained, and the more reactive the halogen is.
Also, the smaller the atom, the less shielding there is.

3)  Have higher melting and boiling points because the atoms are heavier.

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